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Preventing Hydrogen Embrittlement: The Role of Barrier Coatings for the Hydrogen Economy

2023/05/17 by Marcel Wetegrove, María Jazmin Duarte, K. Taube +5 · 1 voice
Engineering · Materials Science · #High-Temperature Coating Behaviors #Hydrogen embrittlement and corrosion behaviors in metals #Nuclear Materials and Properties

paper · pdf · doi:10.3390/hydrogen4020022

openalex publication_date 2023/05/17 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22

Abstract

Hydrogen barrier coatings are protective layers consisting of materials with a low intrinsic hydrogen diffusivity and solubility, showing the potential to delay, reduce or hinder hydrogen permeation. Hydrogen barrier coatings are expected to enable steels, which are susceptible to hydrogen embrittlement, specifically cost-effective low alloy-steels or light-weight high-strength steels, for applications in a hydrogen economy. Predominantly, ceramic coating materials have been investigated for this purpose, including oxides, nitrides and carbides. In this review, the state of the art with respect to hydrogen permeation is discussed for a variety of coatings. Al2O3, TiAlN and TiC appear to be the most promising candidates from a large pool of ceramic materials. Coating methods are compared with respect to their ability to produce layers with suitable quality and their potential for scaling up for industrial use. Different setups for the characterisation of hydrogen permeability are discussed, using both gaseous hydrogen and hydrogen originating from an electrochemical reaction. Finally, possible pathways for improvement and optimisation of hydrogen barrier coatings are outlined.

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