2021/07/06 by K. A. Kovalenko, Konstantin A. Kovalenko, Аndrei S. Potapov +3
Chemistry · Engineering · Materials Science · #Covalent Organic Framework Applications #Membrane Separation and Gas Transport #Metal-Organic Frameworks: Synthesis and Applications
paper · doi:10.1070/rcr5026
openalex publication_date 2021/07/06 · crossref created 2021/07/06 · crossref issued 2022/04/01 · crossref published 2022/04/01 · crossref published-online 2022/04/01 · crossref published-print 2022/04/01 · crossref deposited 2024/04/01 · openalex created_date 2025/10/10 · crossref indexed 2026/07/31 · openalex updated_date 2026/08/04
The review presents data on the use of porous metal-organic frameworks for the separation of some industrially important hydrocarbon mixtures, such as ethane and ethylene, propane and propylene, benzene and cyclohexane, and xylene isomers. It is shown that enhancing the efficiency of materials based on porous metal-organic frameworks relies on understanding the nature of adsorption sites in their structures, the specifics of interactions between the framework and a particular substrate, and the structural response of the framework (host) as it is filled with guest molecules. The achievements of fundamental studies and unresolved problems related to the use of porous metal-organic frameworks in industrial hydrocarbon separation processes are critically analyzed.<br> The bibliography includes 183 references.