2019/05/16 by Olga A. Zalevskaya, O. A. Zalevskaya, Yana A. Gur’eva +2
Biochemistry, Genetics and Molecular Biology · Chemistry · #Asymmetric Hydrogenation and Catalysis #Chemical Synthesis and Analysis #Crystal structures of chemical compounds
paper · doi:10.1070/rcr4880
openalex publication_date 2019/05/16 · crossref created 2019/05/16 · crossref issued 2019/10/01 · crossref published 2019/10/01 · crossref published-print 2019/10/01 · crossref deposited 2023/05/31 · openalex created_date 2025/10/10 · crossref indexed 2026/07/31 · openalex updated_date 2026/08/04
Published data on the synthesis and catalytic properties of metal complexes with chiral ligands containing a terpene moiety are integrated and systematized. The stereochemical features of transition metal complexes with terpene ligands are discussed. Structures of stable complexes of this type and the initial chiral ligands are presented. In view of the enormous structural diversity of the analyzed data, classification is based on the chemical functionality of terpene ligands. The results of application of terpene ligands in asymmetric transition metal catalysis are considered; the data are classified in terms of the type of chemical reaction. Data on the biological activity of some metal complexes with terpene ligands are presented. The bibliography includes 228 references.