2012/08/01 by E. V. Kabin, Evgeniy V. Kabin, V. A. Emel’yanov +8 · 1 citation
Materials Science · #Catalytic Processes in Materials Science #Lanthanide and Transition Metal Complexes #Magnetism in coordination complexes
paper · doi:10.1134/s0036023612050105
crossref issued 2012/08/01 · crossref published 2012/08/01 · crossref published-print 2012/08/01 · openalex publication_date 2012/08/01 · crossref created 2012/08/15 · crossref published-online 2012/08/16 · openalex created_date 2025/10/10 · crossref deposited 2026/04/03 · crossref indexed 2026/07/28 · openalex updated_date 2026/07/29
The reaction of trans -[RuNO(NH 3 ) 4 (OH)]Cl 2 with nitric acid has been studied. Reaction products have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray diffraction, and chemical analysis. Synthesis methods have been developed for amminenitrosoruthenium complexes containing outer-sphere and coordinated nitrate ions: trans -[RuNO(NH 3 ) 4 (H 2 O)](NO 3 ) 3 ( I ), trans -[RuNO(NH 3 ) 4 (NO 3 )](NO 3 ) 2 ( II ), and fac -[RuNO(NH 3 ) 2 (NO 3 ) 3 ] ( III ). Complex II has two polymorphs: monoclinic and tetragonal. The latter has been studied by X-ray crystallography.