Cobalt-catalyzed enantioselective radical hydroamination of alkenes with N -fluorobenzenesulfonimides: theoretical insight of enantio-determining S N 2-like reductive elimination

2025/01/01 by Yu-Jie Liang, Bo Zhu, Yabin Jiang +1 · 1 voice
Chemistry · #Catalytic C–H Functionalization Methods #Radical Photochemical Reactions #Synthesis and Catalytic Reactions

paper · doi:10.1039/d5qo00696a

openalex publication_date 2025/01/01 · openalex created_date 2025/05/29 · openalex updated_date 2026/07/03

Abstract

Enantio-determining S N 2-like reductive elimination of cobalt-catalyzed radical hydroamination of alkenes with N -fluorobenzenesulfonimides has been theoretically disclosed.

Citations

• Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
• Formulation of the reaction coordinate
• New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

Discussions

• 👉 The #cobalt-catalyzed #enantioselective radical hydroamination of alkenes with N-fluorobenzenesulfonimides has been systematically investigated using #DFT calculations. Read full page if you are i [bsky, 0 points, 0 comments]