Solving the cellulose I polymorphic structural riddle: disorder in hydrogen bond networks activates diagnostic terahertz dynamics

2025/01/01 by Emily A Verhaeg, Hiromichi Hoshina, Jun Kikuchi +2 · 1 voice
Agricultural and Biological Sciences · Materials Science · #Liquid Crystal Research Advancements #Plant and Biological Electrophysiology Studies

paper · doi:10.1039/d5tc01544h

openalex publication_date 2025/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01

Abstract

Disorder in cellulose hydrogen-bond networks activates distinct terahertz vibrations, enabling direct spectroscopic differentiation of subtle polymorphic structures.

Citations

• Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr
• A consistent and accurateab initioparametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
• Synthesis of cellulose by Acetobacter xylinum. 2. Preparation of freeze-dried cells capable of polymerizing glucose to cellulose
• Generalized Gradient Approximation Made Simple

Discussions

• Issue 30 for @JMaterChem C is available now! Front cover: "Solving the cellulose I polymorphic structural riddle: disorder in hydrogen bond networks activates diagnostic terahertz dynamics" by Hiromi [bsky, 0 points, 0 comments]