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New lead barium borate glass system for radiation shielding applications: impacts of copper (II) oxide on physical, mechanical, and gamma-ray attenuation properties

2024/05/23 by M.I. Sayyed, M. I. Sayyed, Aljawhara H. Almuqrin +2
Materials Science · #Glass properties and applications #Nuclear materials and radiation effects #Radiation Shielding Materials Analysis

paper · doi:10.1515/ract-2024-0275

openalex publication_date 2024/05/23 · crossref created 2024/05/23 · crossref issued 2024/05/24 · crossref published 2024/05/24 · crossref published-online 2024/05/24 · crossref deposited 2024/10/04 · crossref published-print 2024/10/28 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01 · crossref indexed 2026/08/01

Abstract

Abstract The current work seeks to develop a novel CuO-doped lead calcium barium borate glass using the melt quenching method at 1100 °C. There was a 3.91–4.49 g/cm 3 change in the fabricated glasses’ density, with a respective 0–15 mol.% increase in the CuO concentration. Additionally, substituting CuO for B 2 O 3 reduced the fabricated glasses mechanical properties due to the decreased dissociation energy between 63.99 and 60.50 kcal/cm 3 , and the packing factor decreased between 15.22 and 13.23 cm 3 /mol. Through increasing the fabricated glasses’ CuO concentration, there was a decrease in the bulk, longitudinal, shear, and mechanical Young moduli. Moreover, Monte Carlo simulation (energy interval: 0.033–2.506 MeV) was employed to evaluate the fabricated glasses’ ability to shield gamma rays. A 0–15 mol.% increase in the CuO concentration raised the linear attenuation coefficient (LAC) between 14.081 and 16.797 cm −1 (0.059 MeV), 0.325–0.371 cm −1 (0.662 MeV), and 0.154–0.176 cm −1 (2.506 MeV). The LAC enhancement reduced the required half value thickness of the fabricated glasses by 16.2 %, 12.53 %, and 12.85 % at the of 0.059, 0.662, and 2.506 MeV gamma ray energies.

Citations