Polyoxoniobates with the long-sought feature of face-sharing octahedra stabilized by Te( iv ): a synthetic analogue of natural minerals

2025/11/08 by Ni Zhen, Runhan Li, Binghui Xue +9 · 1 voice
Chemistry · Materials Science · #Crystal Structures and Properties #Inorganic Chemistry and Materials #Polyoxometalates: Synthesis and Applications

paper · doi:10.1039/d5qi02031j

openalex created_date 2025/11/08 · openalex publication_date 2025/11/08 · openalex updated_date 2026/06/11

Abstract

The first polyoxoniobate featuring the long-sought face-sharing octahedra, as observed in natural minerals, has been successfully synthesized using highly charged Te( iv ) ions.

Discussions

• Hot research by Ya-Qian Lan 𝘦𝘵 𝘢𝘭. [(Nb₁₃O₄₂){Te₃(B-α-TeNb₉O₃₃)}₄] (1a) and its trivacant structure [(Nb₁₀O₃₆){Te₃(B-α-TeNb₉O₃₃)}₄] (2a) with the long-sought feature of face-sharing {NbO₆} octah [bsky, 0 points, 0 comments]

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