Structural design and functional characterization of dicationic pyrazolium salts as organic ionic plastic crystals

2025/11/13 by Jong Chan Shin, Suyeon Kim, Eunji Yun +1 · 1 voice
Chemical Engineering · Chemistry · Materials Science · #Characterization (materials science) #Derivative (finance) #Ionic bonding #Ionic conductivity #Ionic liquids properties and applications #N-Heterocyclic Carbenes in Organic and Inorganic Chemistry #Organic and Molecular Conductors Research #Phase (matter) #Plastic crystal

paper · doi:10.1039/d5qm00697j

openalex created_date 2025/11/13 · openalex publication_date 2025/11/13 · openalex updated_date 2026/06/26

Abstract

New organic ionic plastic crystals based on 1,4-bis[ N -( N ′-alkylpyrazolium)]butane PF 6 − salts exhibit unique phase transition behaviors. The octyl derivative with LiTf 2 N mixture showed ionic conductivity 1.31 × 10 −3 S cm −1 at 70 o C.

Citations

• Organic ionic plastic crystals: recent advances

Discussions

• Recent research by Minjae Lee 𝘦𝘵 𝘢𝘭. #KunsanNationalUniversity A series of dicationic pyrazolium hexafluorophosphate (PF₆⁻) salts connected by a butylene bridge were synthesized with side linear [bsky, 0 points, 0 comments]

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