Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

2024/11/05 by Lijun You, Daniel Roth, Lutz Greb · 1 voice
Chemistry · #Synthesis and characterization of novel inorganic/organometallic compounds #Organophosphorus compounds synthesis #Organometallic Complex Synthesis and Catalysis

paper · pdf · doi:10.1039/d4sc06581f

openalex publication_date 2024/11/05 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/31

Abstract

a concerted, highly regio- and diastereoselective mechanism. This unique reactivity opens pathways to novel seven-membered phosphorus heterocycles with customizable optical properties and a structurally varied array of ligands for transition metal coordination.

Citations

• A generally applicable atomic-charge dependent London dispersion correction
• r2SCAN-3c: A “Swiss army knife” composite electronic-structure method

Discussions

• The Focus article was inspired by a recent article from Lijun You, Daniel Roth & Lutz Greb, titled: 'Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a [bsky, 1 points, 1 comments]

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