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Enhancing Acacia dealbata valorization through microwave-assisted autohydrolysis: An energy-efficient approach to oligosaccharides and bioethanol production

2025/06/17 by Álvaro Lobato-Rodríguez, Beatriz Gullón, Gil Garrote +1 · 1 voice
Engineering · Agricultural and Biological Sciences · #Biofuel production and bioconversion #Catalysis for Biomass Conversion #Polysaccharides and Plant Cell Walls

paper · doi:10.1016/j.psep.2025.107470

openalex publication_date 2025/06/17 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/25

Abstract

Microwave-assisted autohydrolysis (MAA) has gained attention as an alternative to conventional hydrothermal treatment (CHT) to solubilize hemicellulosic-derived compounds, such as oligosaccharides, within shorter residence times. MAA assays were conducted on Acacia dealbata wood, an invasive species, at severities (S 0 ) ranging from 3.63 to 4.64 to optimize xylooligosaccharides (XO) recovery and assess the enzymatic susceptibility of the spent solids for bioethanol production. S 0 between 3.77 and 4.15 yielded XO concentrations >9.8 g/L corresponding to a recovery of >80% regarding initial xylan. Besides, at S 0 =3.77, a bioethanol yield of 71% was attained (26.25 g/L). Furthermore, CHT was performed at S 0 values of 3.80 and 4.44 to compare the impact of both heating strategies under optimal conditions for (i) XO production and (ii) higher enzymatic susceptibility of the spent solid. MAA resulted in higher bioethanol yields and, particularly under harsher conditions, lower by-products formation and higher oligosaccharides content. Additionally, MAA consumed 2.60–2.75-fold less energy than CHT.

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