2-Fluorobenzyl ( Z )-2-(5-chloro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate dimethyl sulfoxide monosolvate

2025/10/03 by Aidan P. McKay, David B. Cordes, Mohd Abdul Fatah Abdul Manan · 1 voice
Chemistry · #Synthesis and Biological Evaluation #Synthesis and Reactions of Organic Compounds #Synthesis and biological activity

paper · doi:10.1107/s2414314625008491

openalex publication_date 2025/10/03 · openalex created_date 2025/10/04 · openalex updated_date 2026/06/11

Abstract

In the title solvate, C 16 H 11 ClFN 3 OS 2 ·C 2 H 6 OS, the C=N bond adopts a Z -configuration facilitating the formation of an intramolecular N—H...O hydrogen bond to the carbonyl O atom in an S (6) loop. The dimethylsulfoxide solvent molecule accepts a strong discrete N—H...O hydrogen bond from the γ-lactam grouping. In the extended structure, C ar —H...S hydrogen bonds and quasi-Type I/II Cl...F halogen...halogen bonds are observed, while adjacent dimethyl sulfoxide molecules form S...O chalcogen-bonded chains.

Discussions

• Somewhat belatedly, our latest accepted paper with collaborators at the Universiti Teknologi MARA, Malaysia, formerly @standrewschem.bsky.social. Published in @iucrdata.iucr.org (doi.org/10.1107/S241. [bsky, 1 points, 0 comments]

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