2026/01/01 by Haichao Zhou, Kiyonori Takahashi, Takuya Okamoto +2 · 1 voice
Engineering · Materials Science · #Perovskite Materials and Applications #Organic and Molecular Conductors Research #2D Materials and Applications
paper · pdf · doi:10.1039/d5mh02322j
openalex publication_date 2026/01/01 · openalex created_date 2026/01/29 · openalex updated_date 2026/06/11
tetrahedra in the yellow-emitting isomer mark the crystal isomerism, leading to distinct optical properties. The green-emitting crystals exhibit short excitonic lifetimes, whereas the radiative recombination in the yellow-emitting crystals is delayed by several hundred nanoseconds and redshifted, indicating a self-trapped exciton behaviour with a large Huang-Rhys factor and high activation energy. The structural and optical properties of the isomeric single crystals offer insights into the importance of developing 0D metal halides with multi-colour and delayed emission for sensors, LEDs, and displays.