High-nuclearity Ag-substituted tetrameric sandwich-type polyoxometalates for excellent catalytic performance in C–C bond formation

2025/01/01 by Yahao Sun, Minzhen Cai, Hanhan Chen +3 · 1 voice
Chemistry · Materials Science · #Chemical Synthesis and Reactions #Metal-Organic Frameworks: Synthesis and Applications #Polyoxometalates: Synthesis and Applications

paper · doi:10.1039/d5qi00968e

openalex publication_date 2025/01/01 · openalex created_date 2025/08/07 · openalex updated_date 2026/06/26

Abstract

A tetrameric sandwich-type high-nuclearity substituted silver cluster with Lewis acid–base sites was synthesized and demonstrated outstanding catalytic performance in C–C bond formation for the Knoevenagel condensation and cyanosilylation reactions.

Discussions

• 🔥𝐇𝐢𝐠𝐡-𝐧𝐮𝐜𝐥𝐞𝐚𝐫𝐢𝐭𝐲 𝐀𝐠-𝐬𝐮𝐛𝐬𝐭𝐢𝐭𝐮𝐭𝐞𝐝 𝐭𝐞𝐭𝐫𝐚𝐦𝐞𝐫𝐢𝐜 𝐬𝐚𝐧𝐝𝐰𝐢𝐜𝐡-𝐭𝐲𝐩𝐞 𝐩𝐨𝐥𝐲𝐨𝐱𝐨𝐦𝐞𝐭𝐚𝐥𝐚𝐭𝐞𝐬 𝐟𝐨𝐫 𝐞𝐱𝐜𝐞𝐥𝐥𝐞𝐧𝐭 𝐜𝐚𝐭𝐚𝐥𝐲𝐭𝐢𝐜 𝐩𝐞𝐫𝐟𝐨𝐫𝐦� [bsky, 1 points, 0 comments]

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