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Nanodroplet-Confined Electroplating Enables Submicron Printing of Metals and Oxide Ceramics

2026/01/31 by Mirco Nydegger, Rebecca A. Gallivan, Arthur Barras +2 · 1 voice
Engineering · #Electrohydrodynamics and Fluid Dynamics #Electrophoretic Deposition in Materials Science #Nanomaterials and Printing Technologies

paper · doi:10.1021/acsnano.6c01486

openalex publication_date 2026/06/10 · openalex created_date 2026/06/11 · openalex updated_date 2026/07/27

Abstract

The fabrication of functional micro- and nanoelectronic devices requires the deposition of high-quality materials from different electronic material classes, such as conductors, semiconductors, and insulators. Establishing ultrahigh-resolution additive manufacturing as a viable addition to existing fabrication methods requires the combinatorial additive deposition of different electronic material classes. However, current techniques do not provide such a capability. Here, we demonstrate that droplet-confined electroplating, an ultrahigh-resolution additive manufacturing technique initially developed for metals as electrohydrodynamic redox printing (EHD-RP), allows the direct deposition of not only many metals but also metal oxides. Particularly, we demonstrate that applying fundamental electrochemical principles in combination with on-the-fly switching of the deposited material allows for the direct codeposition of metals, metal hydroxides, and metal oxides. Our results demonstrate the feasibility of leveraging simple water-based electrochemical concepts to produce intricate and multimaterial structures at the nanoscale.

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