2025/01/07 by Jairo Obando-Guevara, Álvaro González-García, Marcin Rosmus +5 · 1 voice
Materials Science · Physics and Astronomy · #2D Materials and Applications #Surface and Thin Film Phenomena #Electronic and Structural Properties of Oxides
paper · doi:10.1021/acsnano.4c13992
openalex publication_date 2025/01/07 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22
We experimentally observe quantum confinement states in bulk MoS 2 by using angle-resolved photoemission spectroscopy (ARPES). The band structure at the Γ̅ point reveals quantum well states (QWSs) linked to vertical quantum confinement of the electrons, confirmed by the absence of dispersion in k z and a strong intensity modulation with the photon energy. Notably, the binding energy dependence of the QWSs versus n does not follow the quadratic dependence of a two-dimensional electron gas. Instead, a linear behavior is observed that is consistent with a parabolic-like quantum well. This confinement arises from the mechanical exfoliation preparation method, which leads to the detachment of a multilayer stack from the underlying bulk. This is confirmed by density functional theory (DFT) calculations. The quantum confinement in bulk-like MoS 2 not only offers the opportunity to explore intersubband transitions to exploit optical properties but also provides a means to study fundamental quantum phenomena in multilayer stacks of different thicknesses.