High performance single-molecule magnets, Orbach or Raman relaxation suppression?

2020/01/01 by Alejandro Castro‐Álvarez, Yolimar Gil, Leonel Llanos +1 · 1 voice
Materials Science · #Lanthanide and Transition Metal Complexes #Magnetism in coordination complexes #Organic and Molecular Conductors Research

paper · doi:10.1039/d0qi00487a

openalex publication_date 2020/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/02

Abstract

Relaxation mechanisms limiting the blocking temperature for high-performance single molecule magnets (SMMs) are investigated. Best SMMs are limited by the exponential regime. Current <italic>ab initio</italic> methods can yield accurate estimations for this limit.

Discussions

• 🏆Check out one of ICF Outstanding paper “High performance single-molecule magnets, Orbach or Raman relaxation suppression?” 🎉Join us in celebrating the authors！ 🔗Read the full article: doi.org/10 [bsky, 2 points, 0 comments]

Related

• A Caveat for Single-Molecule Magnetism: Non-linear Arrhenius Plots
• An operational definition of the 100 second blocking temperature\n T_\B100 for single molecule magnets
• Field-induced oscillation of magnetization blocking in holmium metallacrown magnet
• Utilizing a Bulky Ligand to Regulate Orbach, Raman, and QTM Relaxation Processes in a Series of O h ‐Type Dy(III)‐Based Single‐Molecule Magnets
• Molecular spin relaxation of f-block metal complexes for quantum applications in a nutshell (Review article)