Electrochemical Minisci-type trifluoromethylation of electron-deficient heterocycles mediated by bromide ions

2019/01/01 by Gui-Yuan Dou, Yangye Jiang, Kun Xu +1 · 1 voice
Pharmacology, Toxicology and Pharmaceutics · Chemistry · #Fluorine in Organic Chemistry #Radical Photochemical Reactions #Inorganic Fluorides and Related Compounds

paper · doi:10.1039/c9qo00552h

openalex publication_date 2019/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/05/21

Abstract

An electrochemical methodology for the Minisci-type trifluoromethylation of electron-deficient heterocycles mediated by cheap and easily available bromide ions has been developed.

Discussions

• 🏆We are delighted to present another OCF Outstanding Paper by Cheng-Chu Zeng et al. 👉Electrochemical Minisci-type trifluoromethylation of electron-deficient heterocycles mediated by bromide ions [bsky, 2 points, 0 comments]

Related

• Selective Electrochemical Defluorinative Hydroxymethylation toward Difluoro-Substituted Alcohol Building Blocks
• Recent Advances in the Electrochemical Defluorinative Transformations of C—F Bonds
• Radical trifluoromethylation
• para-Selective, Direct C(sp²)–H Alkylation of Electron-Deficient Arenes by the Electroreduction Process
• Heterocyclic biradicaloid for singlet fission: cleavage of bromine atoms from precursor 3,6-dibromo-1,4-dimethyl-piperazine-2,5-dione