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Half-sandwich scandium methylidenes

2025/01/01 by Gernot T. L. Zug, Sylvia Zeiner, Jonas Reuter +3 · 1 voice
Chemistry · #Synthesis and characterization of novel inorganic/organometallic compounds

paper · pdf · doi:10.1039/d5qi00152h

openalex publication_date 2025/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/26

Abstract

Methylidene nucleophilicity is significantly affected by the ancillary ligand and type of group 13 methyl compound, revealed by Sc–CH 2 bonding metrics and 13 C NMR spectroscopy.

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