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Exotic Photothermal Response in Ti‐Based MXene Optoelectronic Devices

2025/04/14 by Stefano Ippolito, Francesca Urban, Paolo Samorı́ +2 · 1 voice · 1 citation
Materials Science · Engineering · #MXene and MAX Phase Materials #Advanced Memory and Neural Computing #2D Materials and Applications

paper · pdf · doi:10.1002/aelm.202500017

openalex publication_date 2025/04/14 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22

Abstract

Abstract MXenes represent one‐of‐a‐kind materials to devise radically novel technologies and achieve breakthroughs in optoelectronics. To exploit their full potential, precise control over the influence of stoichiometry on optical and thermal properties, as well as device performance, must be achieved. Here, the characteristics of optoelectronic devices based on Ti 3 C 2 T x and Ti 2 CT x thin films are uncovered, highlighting the striking difference in their photothermal responses to laser irradiation under different experimental conditions. Even though their absorption coefficients at 450 nm are comparable, the thermal excitation and relaxation phenomena display markedly different kinetics: Ti 2 CT x devices show a strong asymmetry during the heating‐cooling cycle, with the heat dissipation kinetics being three orders of magnitude slower than Ti 3 C 2 T x and strongly influenced by environmental conditions. The findings are expected to stimulate fundamental investigations into the photothermal response of MXenes and open exciting prospects for their use in printed and wearable optoelectronics, including memory devices and neuromorphic computing.

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