Fe( ii ) bidentate complexes with long-lived triplet states

2025/01/01 by Ulises Carrillo, Ronan Viel, Salwa Simona Jamil +7 · 1 voice · 1 citation
Chemistry · Materials Science · #Lanthanide and Transition Metal Complexes #Magnetism in coordination complexes #Metal-Catalyzed Oxygenation Mechanisms

paper · pdf · doi:10.1039/d5qi01105a

openalex publication_date 2025/01/01 · openalex created_date 2025/08/27 · openalex updated_date 2026/08/01

Abstract

The excitation of bidentate quinoline/quinoxaline-NHC iron( ii ) complexes at 530 nm produced 3 MC/ 3 MLCT mixed excited states with lifetimes up to 74 ps.

Cited by

• Synthetic Mechanism of a Fe(II) N -Heterocyclic Carbene Bidentate Complex Revealed by Electronic Structure Methods

Discussions

• 👉 𝐅𝐞(𝐈𝐈) 𝐛𝐢𝐝𝐞𝐧𝐭𝐚𝐭𝐞 𝐜𝐨𝐦𝐩𝐥𝐞𝐱𝐞𝐬 𝐰𝐢𝐭𝐡 𝐥𝐨𝐧𝐠-𝐥𝐢𝐯𝐞𝐝 𝐭𝐫𝐢𝐩𝐥𝐞𝐭 𝐬𝐭𝐚𝐭𝐞𝐬 by Philippe C. Gros 𝘦𝘵 𝘢𝘭. Fe²⁺ complexes with bidentate quinoline/quinoxaline- #NHC l [bsky, 2 points, 0 comments]

Related

• Iron(III) Complexes with Luminescence Lifetimes of up to 100 ns to Enhance Upconversion and Photocatalysis
• 60 K wide hysteresis embracing room temperature in a fluorescent Fe II spin transition complex
• A Heterodox Approach for Designing Iron Photosensitizers: Pentacyanoferrate(II) Complexes with Monodentate Bipyridinium/Pyrazinium-Based Acceptor Ligands
• Synthetic Mechanism of a Fe(II) N -Heterocyclic Carbene Bidentate Complex Revealed by Electronic Structure Methods
• Bidirectional photoswitchability in an iron( iii ) spin crossover complex: symmetry-breaking and solvent effects