Uncovering diverse reactivity of NHCs with diazoalkane: C–H activation, CC bond formation, and access to N-heterocyclic methylenehydrazine

2024/01/01 by Kajal Balayan, Himanshu Sharma, Kumar Vanka +2 · 1 voice
Chemistry · #N-Heterocyclic Carbenes in Organic and Inorganic Chemistry #Cyclopropane Reaction Mechanisms #Catalytic Cross-Coupling Reactions

paper · doi:10.1039/d4sc05740f

openalex publication_date 2024/01/01 · openalex created_date 2024/10/09 · openalex updated_date 2026/05/21

Abstract

N and KHMDS to form N-heterocyclic methylene hydrazine, 5. Theoretical calculations have been conducted to elucidate the diverse mechanisms underlying product formation.

Discussions

• Our recent paper at Chemical Science describing diverse reactions of NHCs towards TMSCHN2 #maingroupchemistry #Carbene doi.org/10.1039/D4SC... [bsky, 3 points, 0 comments]

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