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Chemistry of chromian spinel in volcanic rocks as a potential guide to magma chemistry

1992/06/01 by Shoji Arai · 3 citations
Earth and Planetary Sciences · #Geochemistry and Elemental Analysis #Geological and Geochemical Analysis #High-pressure geophysics and materials

paper · doi:10.1180/minmag.1992.056.383.04

crossref issued 1992/06/01 · crossref published 1992/06/01 · crossref published-print 1992/06/01 · openalex publication_date 1992/06/01 · crossref created 2006/12/07 · crossref published-online 2018/07/05 · crossref deposited 2021/02/04 · openalex created_date 2025/10/10 · crossref indexed 2026/07/30 · openalex updated_date 2026/07/30

Abstract

Abstract Chromian spinel in volcanic rocks is a potential discriminant for magma chemistry. The TiO 2 content of spinel, compared at similar Fe 3+ /(Cr + Al + Fe 3+ ) ratios, can distinguish island arc basalts from intraplate basalts. MORB spinels are low in this ratio and are intermediate for the TiO 2 level at comparable Fe 3+ ratios. Spinels from back-arc basin basalts, although similar in TiO 2 /Fe 3+ ratio, are more enriched in Fe 3+ than the MORB spinels. Spinels in the oceanic plateau basalts are distinctly lower in TiO 2 than other intraplate basalt spinels and even slightly lower in TiO 2 than the MORB spinels. The data were successfully applied to estimate the kind of the magma from which spinelbearing cumulates, especially dunites, were formed. Original magma chemistry of altered or metamorphosed volcanics in which spinels survive can also be estimated by the chemistry of relict spinel alone. It is possible to estimate the magma type of source volcanics for detrital spinel particles of volcanic derivation.

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