From boom to bloom: synthesis of diazidodifluoromethane, its stability and applicability in the ‘click’ reaction

2024/11/20 by Mykyta Ziabko, S. Yu. Suikov, Josef Filgas +7 · 1 voice
Chemistry · Pharmacology, Toxicology and Pharmaceutics · #Chemical Reactions and Isotopes #Click Chemistry and Applications #Fluorine in Organic Chemistry

paper · pdf · doi:10.1039/d4cc05128a

openalex publication_date 2024/11/20 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/11

Abstract

calculations. Copper(I)-catalysed azide-alkyne cycloaddition of the title azide with alkynes afforded difluoromethylene-containing bis(1,2,3-triazoles)amenable to Rh(II)-catalysed transannulation with nitriles to difluoromethylene bis(imidazoles).

Citations

• The ORCA quantum chemistry program package

Discussions

• 📜 Ziabko, M.; Suikov, S.; Filgas, J.; Slavíček, P.; Gazdurová, M.; Bednárová, L.; Matyáš, R.; Klepetářová, B.; David, T.; Beier, P. From boom to bloom: synthesis of diazidodifluoromethane, its stabil [bsky, 3 points, 0 comments]

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