Preparation and Molecular Structure of (Methoxo)(octaethylporphinato)iron (III)

1990/06/01 by Keiichiro Hatano, Tadayuki Uno
Chemistry · Materials Science · Medicine · #Metal complexes synthesis and properties #Metal-Catalyzed Oxygenation Mechanisms #Porphyrin and Phthalocyanine Chemistry

paper · doi:10.1246/bcsj.63.1825

crossref issued 1990/06/01 · crossref published 1990/06/01 · crossref published-print 1990/06/01 · openalex publication_date 1990/06/01 · crossref published-online 2006/06/05 · crossref created 2006/07/26 · crossref deposited 2024/01/19 · openalex created_date 2025/10/10 · crossref indexed 2026/07/29 · openalex updated_date 2026/07/30

Abstract

Abstract The X-ray structure of Fe(OEP)(OMe) is reported: Fe(C36H44N4)(CH3O), F.W.=619.7, monoclinic, P21/c, a=13.412(5) Å, c=18.912(8) Å, β=106.28(3)° and V=3348(4) Å3, Z=4. A methoxide-coordinated iron(III) porphyrinate with π-π dimeric porphyrin interaction in the solid state was revealed. The facile formation of the methoxide is briefly discussed.

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