2025/01/01 by Matthias Schöbinger, Martin Huber, Berthold Stöger +2 · 1 voice
Chemistry · #Organometallic Compounds Synthesis and Characterization #Synthesis and Characterization of Heterocyclic Compounds #Synthesis of Tetrazole Derivatives
paper · pdf · doi:10.1039/d5ce00197h
openalex publication_date 2025/01/01 · openalex created_date 2025/03/20 · openalex updated_date 2026/07/09
C), ATR-IR, UV-vis and photoluminescence spectroscopy as well as PXRD. Eleven distinct coordination compounds are reported, each falling into one of four classes: the first group (I) comprises of a mononuclear complex, whereas group (II) consists of dinuclear complexes with ligand bridged metal centers (Ag(i)) and weak intermetallic interactions (∼4 Å). Group (III) likewise includes dinuclear complexes, but the bridging mode was prevented and the Ag-Ag distance was reduced (∼3.2 Å) upon the addition of a co-ligand. Group (IV), a structurally diverse category consists of coordination polymers, which in some cases show even shorter intermetallic contacts (<3.1 Å). All investigated coordination compounds exhibit photoluminescence in the solid state, with structurally dependent emission maxima distinct from those of the ligand.