Colour tuneability of heteroleptic iridium complexes through second-sphere coordination

2024/01/01 by Barbora Balónová, T. Harri Jones, Allison E. True +2 · 1 voice
Engineering · Materials Science · #Lanthanide and Transition Metal Complexes #Magnetism in coordination complexes #Organic Light-Emitting Diodes Research

paper · pdf · doi:10.1039/d4ra04535a

openalex publication_date 2024/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/22

Abstract

(N^N)] were synthesised, characterised and their photophysical properties determined. The incorporated guanidine moieties allow us to introduce a hydrogen-bonding array for the formation of self-assembled iridium-bound hydrogen-bonded systems. Through a series of experimental and computational studies we demonstrated the host-guest chemistry of these systems. These hydrogen-bonding interactions were shown to have significant impacts on chromaticity, quantum yields and lifetimes with emphasis on energy transfer studies based on this second-sphere coordination approach.

Discussions

• We would like to highlight the winner of the RSC Advances Outstanding Student Paper Award 2024 in the Inorganic Chemistry category, T. Harri Jones, for his contribution in doi.org/10.1039/D4RA... 🏆Co [bsky, 4 points, 0 comments]

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