Судьба профессора Н. Н. Розенталя (1892–1960)

2013/01/01 by Jian Wei, Ruwei Yao, Yu Han +3 · 1 citation
Chemical Engineering · Chemistry · Social Sciences · #Asymmetric Hydrogenation and Catalysis #Carbon dioxide utilization in catalysis #Catalysts for Methane Reforming #Eastern European Communism and Reforms

paper · doi:10.1039/d1cs00260k

openalex publication_date 2013/01/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/06/24

Abstract

The emerging process of CO₂ hydrogenation through heterogenous catalysis into important bulk chemicals provides an alternative strategy for sustainable and low-cost production of valuable chemicals, and brings an important chance for mitigating CO₂ emissions. Direct synthesis of the family of unsaturated heavy hydrocarbons such as α-olefins and aromatics <i>via</i> CO₂ hydrogenation is more attractive and challenging than the production of short-chain products to modern society, suffering from the difficult control between C-O activation and C-C coupling towards long-chain hydrocarbons. In the past several years, rapid progress has been achieved in the development of efficient catalysts for the process and understanding of their catalytic mechanisms. In this review, we provide a comprehensive, authoritative and critical overview of the substantial progress in the synthesis of α-olefins and aromatics from CO₂ hydrogenation <i>via</i> direct and indirect routes. The rational fabrication and design of catalysts, proximity effects of multi-active sites, stability and deactivation of catalysts, reaction mechanisms and reactor design are systematically discussed. Finally, current challenges and potential applications in the development of advanced catalysts, as well as opportunities of next-generation CO₂ hydrogenation techniques for carbon neutrality in future are proposed.

Citations

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Cited by

• Emerging Trends in Advanced Materials for C─S Coupling Reactions: Design Strategies and Future Perspectives

Related

• Recycling Carbon Dioxide through Catalytic Hydrogenation: Recent Key Developments and Perspectives
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