2003/09/11 by Jascha Repp, Gerhard Meyer, Karl-Heinz Rieder +1
Physics and Astronomy · #cond-mat
paper · pdf · doi:10.1103/physrevlett.91.206102
published as Phys. Rev. Lett. 91, 206102 (2003) · 4 pages, 4 figures
arxiv created 2003/09/11 · arxiv updated 2009/12/01
A combined low-temperature scanning tunneling microscopy and density functional theory study on the binding and diffusion of copper monomers, dimers, and trimers adsorbed on Cu(111) is presented. Whereas atoms in trimers are found in fcc sites only, monomers as well as atoms in dimers can occupy the stable fcc as well as the metastable hcp site. In fact the dimer fcc-hcp configuration was found to be only 1.3 meV less favorable with respect to the fcc-fcc configuration. This enables a confined intra-cell dimer motion, which at temperatures below 5 K is dominated by thermally assisted tunneling.