vix.ing · top · new · best · stats · spec

Structure elucidation and NMR assignments for curcuminoids from the rhizomes of Curcuma longa

2009/06/30 by Wei Li, Shisheng Wang, Jiatao Feng +7
Biochemistry, Genetics and Molecular Biology · Medicine · #Biochemical effects in animals #Curcumin's Biomedical Applications #Natural product bioactivities and synthesis

paper · doi:10.1002/mrc.2478

openalex publication_date 2009/06/30 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28

Abstract

Thirteen curcuminoids (1-13) were isolated from the rhizomes of Curcuma longa. Among them, 1,5-dihydroxy-1,7-bis(4-hydroxyphenyl)-4,6-heptadiene-3-one (1), 1,5-dihydroxy-1-(4-hydroxy-3-methoxyphenyl)-7-(4-hydroxyphenyl)-4,6-heptadiene-3-one (2), 1,5-dihydroxy-1-(4-hydroxyphenyl)-7-(4-hydroxy-3-methoxyphenyl)-4,6-heptadiene-3-one (3), and 3-hydroxy-1,7-bis-(4-hydroxyphenyl)-6-heptene-1,5-dione (4) are new compounds, and 1-(4-hydroxyphenyl)-7-(3, 4-dihydroxyphenyl)-1, 6-heptadiene-3, 5-dione (5) is isolated from natural sources for the first time. The structures of these compounds were elucidated by extensive spectroscopic analyses, especially 1D and 2D NMR spectroscopy. The (13)C NMR data and complete (1)H and (13)C NMR assignments of some known compounds are reported for the first time. In addition, the errors of (1)H and (13)C assignments reported in the literature were corrected.

Citations

Related