1995/05/02 by Alexander C. Filippou, Bernhard Lungwitz, Klaus M. A. Wanninger +2 · 1 citation
Chemistry · #Organometallic Complex Synthesis and Catalysis #Synthesis and characterization of novel inorganic/organometallic compounds #Synthetic Organic Chemistry Methods
paper · doi:10.1002/anie.199509241
openalex publication_date 1995/05/02 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/29
Oxidation of half-sandwich chromium complexes of type 1 (R = H, Me) with halogens afforded the first carbyne complexes 2 (X = Cl,Br) of chromium in a high oxidation state. With tBuNC or P(OMe)3 these complexes can be converted into thermally stable products, which were structurally and spectroscopically characterized. Counterion: Cl−, Br−.