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Stable isotopes constrain the genesis of Thar Desert gypsum playas and reveal Holocene paleoenvironmental variability in Northwest India

2025/09/01 by Alena Giesche, Cameron A. Petrie, Yama Dixit +8 · 2 voices · 1 citation
Earth and Planetary Sciences · #Geology and Paleoclimatology Research #Marine and environmental studies #Geological formations and processes

paper · doi:10.1016/j.quascirev.2025.109586

Abstract

Numerous evaporative saline playa lakes exist within the Thar Desert in Northwest India. Some are active seasonally, whereas others are dry and preserve up to several meters of sedimentary deposits. These deposits feature a variety of evaporite minerals, including the hydrated mineral gypsum (CaSO 4 ⋅2H 2 O). The isotopic composition of gypsum hydration water preserves the δ 18 O and δD of paleolake water at the time of gypsum formation. This provides a way to understand the hydrologic balance in a part of the world where it is typically very difficult to obtain any paleoclimate records. We present paleohydrological records from two dry playas (Karsandi, Khajuwala) and one active playa (Lunkaransar) in the Thar Desert using the oxygen and hydrogen isotopic composition of gypsum hydration water. We present a theoretical model to explain differences in how the gypsum records water isotopic composition from perennial playas (consistent paleoclimate recorders) as opposed to seasonally fed or ephemeral playas (that reflect evaporated meteoric water inconsistently). Results suggest that enhanced direct precipitation, with associated higher groundwater and possibly fluvial sources, maintained active playa lake basins in the central Thar Desert for the Early through Middle Holocene. We also examine δ 34 S SO4 , δ 18 O SO4 , and 87 Sr/ 86 Sr of the gypsum sulfate to explore the source and evolution of solutes in the Thar Desert playas. Results indicate that seasalt aerosols likely accumulated in aeolian sands during glacial dry periods and concentrated in playa deposits once a threshold level of moisture was reached in the Early Holocene. By the Late Holocene, after c. 4.4 ka BP, these water sources diminished and some playas were again covered by aeolian deposits. The Thar Desert gypsum deposits provide valuable insight into local moisture balance during a time period that featured important cultural transformation in the surrounding region, including the South Asian Neolithic agricultural societies around 8 ka BP, the full span of the Indus Civilization (5.3–3.3 ka BP), and periods of human occupation after 3 ka BP. • Gypsum in Thar Desert playa lakes preserves past lake water isotopic composition. • Seasalt aerosols accumulated in Thar Desert sands and collected in Holocene playas. • Perennial v. ephemeral playas preserve a distinct gypsum crystal morphology. • Wet Early-Middle Holocene conditions sustained deeper playas than the Late Holocene. • Hydrological changes overlap with key Indus Civilization cultural shifts.

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