2025/08/27 by Mikhail V. Vaganov, Nicolas Suaud, François Lambert +8 · 1 voice · 3 citations
Materials Science · Biochemistry, Genetics and Molecular Biology · #Magnetism in coordination complexes #Electron Spin Resonance Studies #Lanthanide and Transition Metal Complexes
paper · pdf · doi:10.1038/s41557-025-01926-5
Abstract Controlling quantum spins using electric rather than magnetic fields promises substantial architectural advantages for developing quantum technologies. In this context, spins in molecular magnets offer tunability of spin–electric couplings (SECs) by rational chemical design. Here we demonstrate systematic control of SECs in a family of Mn(II)-containing molecules by varying the coordination environment of the spin centre. The trigonal bipyramidal (tbp) molecular structure with C 3 symmetry leads to a substantial molecular electric dipole moment that is directly connected to its magnetic anisotropy. The interplay between these two features gives rise to experimentally observed SECs, which can be rationalized by wavefunction theoretical calculations. Our findings guide strategies for the development of electrically controllable molecular spin qubits for quantum technologies.