Unified Symmetry Breaking in Confined Electrolytes: Charge, Chemical Potential, and the Nonlinear Capacitance of Hollow Nanoparticles

2025/06/06 by Marcelo Lozada‐Cassou, Lozada-Cassou, Marcelo · 1 citation
Chemistry · Engineering · #Electrohydrodynamics and Fluid Dynamics #Electrostatics and Colloid Interactions #FOS: Physical sciences #Nanopore and Nanochannel Transport Studies #Soft Condensed Matter (cond-mat.soft) #Statistical Mechanics (cond-mat.stat-mech)

paper · doi:10.48550/arxiv.2506.05644

openalex publication_date 2025/06/06 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We study the nonlinear electrostatic response of electrolyte-filled, hollow charged nanoparticles, modeled as nanocapacitors with finite wall thickness and curved geometry.

Citations

• Contact theorems for electrolyte-filled hollow charged nanoparticles: Non-linear osmotic pressure in confined electrolytes
• Topological impact of nanopore electrodes on the structure of the electrical double layer and the di erential capacitance
• Extracellular vesicles and nanoparticles: emerging complexities
• Breakdown of electroneutrality in nanopores
• Classical Electrodynamics, 3rd ed .

Cited by

• Topological control of local electroneutrality in confined electrolytes

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