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Structure and dynamics of Fe90Si3O7 liquids close to Earth's liquid core conditions

2023/03/07 by Lin Tang, Chao Zhang, Tang, Ling +9
Earth and Planetary Sciences · Physics and Astronomy · #FOS: Physical sciences #Geological and Geochemical Analysis #Geophysics (physics.geo-ph) #High-pressure geophysics and materials #Materials Science (cond-mat.mtrl-sci) #Theoretical and Computational Physics

paper · pdf · doi:10.48550/arxiv.2303.03585

openalex publication_date 2023/03/07 · openalex created_date 2023/03/10 · openalex updated_date 2026/07/28

Abstract

Using an artificial neural-network machine learning interatomic potential, we have performed molecular dynamics simulations to study the structure and dynamics of Fe90Si3O7 liquid close to the Earth's liquid core conditions. The simulation results reveal that the short-range structural order (SRO) in the Fe90Si3O7 liquid is very strong. About 80% of the atoms are arranged in crystalline-like SRO motifs. In particular, ~70% of Fe-centered clusters can be classified as either hexagonal-close-pack (HCP/HCP-like) or icosahedral (ICO/ICO-like) SRO motifs. The SRO clusters centered on Fe, Si, or O atoms are strongly intermixed and homogenously distributed throughout the liquid. The atomic structure of the liquid and the fractions of dominant SRO clusters are not sensitive to pressure/temperature used in the simulations except that the SRO of the O-centered clusters is enhanced close to inner core pressures. The O diffusion coefficient is about 2-3 times larger than the Fe and Si ions and increases more rapidly in the deeper core regions.

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