2024/06/30 by Emily Y. Chen, Chen, Emily Y., Sujit S. Datta +1 · 2 citations
Chemical Engineering · Materials Science · #Applied Physics (physics.app-ph) #Chaotic Dynamics (nlin.CD) #FOS: Physical sciences #Fluid Dynamics (physics.flu-dyn) #Materials Science (cond-mat.mtrl-sci) #Polymer Foaming and Composites #Rheology and Fluid Dynamics Studies #Soft Condensed Matter (cond-mat.soft)
paper · pdf · doi:10.48550/arxiv.2407.00778
openalex publication_date 2024/06/30 · openalex created_date 2024/07/06 · openalex updated_date 2026/07/28
Diverse chemical, energy, environmental, and industrial processes involve the flow of polymer solutions in porous media. The accumulation and dissipation of elastic stresses as the polymers are transported through the tortuous, confined pore space can lead to the development of an elastic flow instability above a threshold flow rate. This flow instability can generate complex flows with strong spatiotemporal fluctuations, despite the low Reynolds number (Re ≪ 1); for example, in 1D ordered arrays of pore constrictions, this unstable flow can be multistable, with distinct pores exhibiting distinct unstable flow states. Here, we examine how this multistability is influenced by fluid rheology. Through experiments using diverse polymer solutions having systematic variations in fluid shear-thinning or elasticity, in pore constriction arrays of varying geometries, we show that the onset of multistability can be described using a single dimensionless parameter. This parameter, the streamwise Deborah number, compares the stress relaxation time of the polymer solution to the time required for the fluid to be advected between pore constrictions. Our work thus helps to deepen understanding of the influence of fluid rheology on elastic instabilities, helping to establish guidelines for the rational design of polymeric fluids with desirable flow behaviors.