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An early explanation of the periodic table: Lars Vegard and X-ray spectroscopy

2011/12/16 by Helge Kragh, Kragh, Helge
Arts and Humanities · Chemistry · Physics and Astronomy · Social Sciences · #FOS: Physical sciences #History and Philosophy of Physics (physics.hist-ph) #History and advancements in chemistry #International Science and Diplomacy #Twentieth Century Scientific Developments #physics.hist-ph

paper · pdf · doi:10.48550/arxiv.1112.3774

22 pages; 6 figures; 1 table. A shorter version has been submitted to Bulletin for the History of Chemistry

arxiv created 2011/12/16 · openalex publication_date 2011/12/16 · arxiv updated 2011/12/19 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

The Norwegian physicist Lars Vegard may have been the first to propose electron configurations for all the chemical elements, from hydrogen to uranium, on the basis of quantum atomic theory. This he did in papers of 1918-1919 in which he argued that the principal quantum number corresponded to the shells in Bohr's picture of atomic structure. Vegard's theory of the periodic system, based on the methods of theoretical X-ray spectroscopy in particular, was a significant advance but exerted little influence on the further development. It presupposed atoms made up of planar electron rings, and with the abandonment of the ring atom about 1920 this and similar models lost their credibility.

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