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Effect of polymeric additives on ignition, combustion and flame\n characteristics and soot deposits of crude oil droplets

2019/11/01 by Gurjap Singh, Singh, Gurjap, Mehdi Esmaeilpour +3
Chemical Engineering · Engineering · #Advanced Combustion Engine Technologies #Applied Physics (physics.app-ph) #Biodiesel Production and Applications #FOS: Physical sciences #Fire dynamics and safety research

paper · pdf · doi:10.48550/arxiv.1911.00392

openalex publication_date 2019/11/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Many oil fires have resulted from the crude oil train derailments in recent\nyears. Given the importance of crude oil shipping by rail to the energy\nsecurity of the US, it is important to consider various methods that will\ndecrease the likelihood of crude oil catching fire in case of a crude oil\nderailment. Present study examines the effect of polybutadiene polymer on the\ncombustion properties and soot deposits of Bakken and Pennsylvania crudes.\nTreating these crudes as multicomponent liquid fuels and polybutadiene as an\nadditive, droplet combustion experiments were conducted with sub-millimeter\nsized spherical droplets suspended on very fine support fibers. Polybutadiene\npolymer additive of two different chain lengths has been investigated. Results\nshow that both polymer chain length and origin of crude oil have a significant\neffect on various combustion properties like combustion rate, ignition delay,\ntotal combustion time, and flame stand-off ratio. Polymeric additives also\nchange the soot deposit structure and particle size compared to the base fuel.\nPresent research is envisioned to aid in theoretical combustion modeling of\ncomplex multicomponent liquid fuels, as well as generate interest in\ninvestigating more polymeric additives for liquid fuels.\n

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