2022/12/02 by John Çamkıran, Çamkıran, John, Fabian Parsch +3
Economics, Econometrics and Finance · Materials Science · Physics and Astronomy · #Chemical Physics (physics.chem-ph) #Complex Systems and Time Series Analysis #FOS: Physical sciences #Material Dynamics and Properties #Materials Science (cond-mat.mtrl-sci) #Theoretical and Computational Physics
paper · pdf · doi:10.48550/arxiv.2212.01161
openalex publication_date 2022/12/02 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/31
Notwithstanding decades of work, we still lack a satisfactory understanding of the structural relaxation that takes place as a liquid is rapidly cooled to form a glass. The present paper discusses a novel statistical characterization of this phenomenon in Kob-Andersen-type mixtures -- a simple yet powerful class of model glass formers. We use the variance of an order parameter called the extracopularity coefficient to measure the intensity of instantaneous fluctuations in local orientational order. This intensity is found to be nearly composition independent at the onset temperature of glassy dynamics for the standard Kob-Andersen mixture. We decompose these fluctuations into a density and symmetry contribution. Through the behavior of these contributions, we argue that the near composition independence prevails when the structure of the system equally resembles a liquid and a glass. We moreover report that the intensity of local-order fluctuations behaves like a heuristic measure of glass-forming ability, which could prove useful when exact methods are intractable.