Electrochemical Insertion of Sodium into Carbon

1993/12/01 by Marca M. Doeff, Yanping Ma, Steven J. Visco +1 · 16 citations
Engineering · Environmental Science · #Advanced Battery Materials and Technologies #Chemical Synthesis and Characterization #Advancements in Battery Materials

paper · doi:10.1149/1.2221153

Abstract

Electrochemical insertion of sodium ions into carbon using solid polymer electrolytes or organic liquid electrolytes is described. Cells with the configuration ) or Na/liquid electrolyte/C were galvanostatically discharged, charged, and cycled. The extent of insertion into C (i.e., ) was found to be a strong function of the type and particle size of the carbon used, and the reversibility of the process was highly dependent upon the type of electrolyte used. The possibility of designing a sodium ion rocking chair cell is discussed, and a first‐generation example, using a petroleum coke anode, polymer electrolyte, and sodium cobalt bronze cathode is described.

Cited by

• Electrochemically Expandable Soft Carbon as Anodes for Na-Ion Batteries. [europepmc]
• Sustainable Materials for Sustainable Energy Storage: Organic Na Electrodes. [europepmc]
• Bi 2 Se 3 /C Nanocomposite as a New Sodium-Ion Battery Anode Material. [europepmc]
• Tin-Decorated Reduced Graphene Oxide and NaLi 0.2 Ni 0.25 Mn 0.75 O  as Electrode Materials for Sodium-Ion Batteries. [europepmc]
• Electrode Materials for High-Performance Sodium-Ion Batteries. [europepmc]
• Anionic Redox Processes in Maricite- and Triphylite-NaFePO 4 of Sodium-Ion Batteries. [europepmc]
• Solvated Ion Intercalation in Graphite: Sodium and Beyond. [europepmc]
• Mini-Review: Mixed Ionic-Electronic Charge Carrier Localization and Transport in Hybrid Organic-Inorganic Nanomaterials. [europepmc]
• Gas sorption porosimetry for the evaluation of hard carbons as anodes for Li- and Na-ion batteries. [europepmc]
• Enhanced Pseudo-Capacitive Contributions to High-Performance Sodium Storage in TiO 2 /C Nanofibers via Double Effects of Sulfur Modification. [europepmc]
• High-Energy Batteries: Beyond Lithium-Ion and Their Long Road to Commercialisation. [europepmc]
• Development of advanced electrolytes in Na-ion batteries: application of the Red Moon method for molecular structure design of the SEI layer. [europepmc]
• Scalable lignin/graphite electrodes formed by mechanochemistry. [europepmc]
• Borophene as a promising anode material for sodium-ion batteries with high capacity and high rate capability using DFT. [europepmc]
• Electrically conducting films prepared from graphite and lignin in pure water. [europepmc]
• A Review of Carbon Anode Materials for Sodium-Ion Batteries: Key Materials, Sodium-Storage Mechanisms, Applications, and Large-Scale Design Principles. [europepmc]

Related

• High Capacity Anode Materials for Rechargeable Sodium-Ion Batteries
• Manipulating Interphase Chemistry by Endogenous Doping Toward High-Performance Hard Carbon Anodes for Sodium-Ion Batteries
• Sodium Metal Battery using CobaltOxide through in Situ Plating of Sodium\n Metal
• Stabilization of STEP electrolyses in lithium-free molten carbonates
• Enabling Fast Na + Transfer Kinetics in the Whole‐Voltage‐Region of Hard‐Carbon Anodes for Ultrahigh‐Rate Sodium Storage