Trends in the Exchange Current for Hydrogen Evolution
2005/01/01 by Jens K. Nørskov, J. K. Nørskov, T. Bligaard +11 · 71 citations
Energy · Engineering · #Electrocatalysts for Energy Conversion #Fuel Cells and Related Materials #Molecular Junctions and Nanostructures
paper · pdf · doi:10.1149/1.1856988
Abstract
A density functional theory database of hydrogen chemisorption energies on close packed surfaces of a number of transition and noble metals is presented. The bond energies are used to understand the trends in the exchange current for hydrogen evolution. A volcano curve is obtained when measured exchange currents are plotted as a function of the calculated hydrogen adsorption energies and a simple kinetic model is developed to understand the origin of the volcano. The volcano curve is also consistent with Pt being the most efficient electrocatalyst for hydrogen evolution.
Cited by
- DFT study of transition metal clusters TMn (n: 1–6) for the hydrogen evolution reaction (HER)
- Anion-Exchange Membrane Water Electrolyzers
- Recent advances in improving utilization efficiency of precious metal catalysts for hydrogen generation from hydrolysis of ammonia borane
- Grand canonical simulations of electrochemical interfaces in implicit solvation models
- Remarkable performance of triatomic single-cluster catalyst of Ti3@graphdiyne in electrocatalytic nitrogen reduction
- Constant potential energetics of metallic and semiconducting electrodes: A benchmark study on 2D materials
- Synergistic effects of N–F codoping on electronic structure and photocatalytic performance of MoSe2 monolayer: A first-principles investigation
- Defective Biphenylene as High-Efficiency Hydrogen Evolution Catalysts
- Mechanical modulation of reaction rates in electrocatalysis
- A First-Principles Investigation of Goldene for Enhanced Hydrogen Evolution Reaction
- Two-dimensional ferroelectric metal for electrocatalysis
- Region-Resolved Interface Descriptors in III-nitride-nanocluster photocatalysts
- Adsorption energies are necessary but not sufficient to identify good catalysts
- Awakening catalytically active surface of BaRuO3 thin film for alkaline hydrogen evolution
- Site heterogeneity and broad surface-binding isotherms in modern catalysis: Building intuition beyond the Sabatier principle
- Clean and Affordable Hydrogen Fuel from Alkaline Water Splitting: Past, Recent Progress, and Future Prospects
- Non-precious-metal catalysts for alkaline water electrolysis: <i>operando</i> characterizations, theoretical calculations, and recent advances
- Expediting hydrogen evolution through topological surface states on Bi2Te3
- Mechanism of the electrochemical hydrogenation of graphene
- Catalyst GFlowNet for electrocatalyst design: A hydrogen evolution reaction case study
- Breaking the Sabatier Principle by Dynamic Adsorption-Desorption Decoupling in Electrocatalytic Hydrogen Evolution
- Tailoring Metal Nanoclusters for Enhanced Electrocatalytic Reduction of CO <sub>2</sub> to CO
- Insights into the OER, ORR, and HER Activity of a New MXene-Family SnSiGeN4 Photocatalyst for Water Splitting: A First-Principles Study
- Light-driven and green Ullmann homocoupling with a Pd single-atom catalyst
- Role of Electronic Structure on Nitrate Reduction to Ammonium: A Periodic Journey
- β–phase hydroxide-steered inner-hosted metal sites for exceptional hydrogen production
- Enhanced electrocatalytic hydrogen evolution with bimetallic Ru/Pt nanoparticles supported on nitrogen-doped reduced graphene oxide
- Adjacent-Site Proximity as a Dominant Activity Descriptor in Single-Atom Pt Catalysts for Hydrogen Evolution Reaction
- The role of phosphorus in catalytic processes of hydrogen energy technology: a perspective
- Advances, practical applications, and future prospects of layered perovskite oxides (LnBaCo <sub>2</sub> O <sub> 5+ <i>δ</i> </sub> ) for electrocatalysis reactions
- Wafer-Scaled III-Nitrides Nanowire Photocathodes Enabled by Synergistic Dual-Electron Extraction for Efficient Solar-to-Hydrogen Conversion
- Revealing Interface Polarization Effects on the Electrical Double Layer with Efficient Open Boundary Simulations under Potential Control
- High-Throughput Screening of 2D Photocatalyst Heterostructures with Suppressed Electron-Hole Recombination for Solar Water Splitting
- Using nature’s blueprint to expand catalysis with Earth-abundant metals
- Noble-Metal Nanocrystals with Controlled Shapes for Catalytic and Electrocatalytic Applications
- Electrocatalytic Reduction of Nitrate to Ammonia on Low-Cost Ultrathin CoO<sub><i>x</i></sub> Nanosheets
- Two-dimensional MXenes: From morphological to optical, electric, and magnetic properties and applications
- New scaling relationships for the oxygen evolution reaction on single atom catalysts
- Is There Anything Better than Pt for HER?
- Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting
- Single-Atom Vacancy Defect to Trigger High-Efficiency Hydrogen Evolution of MoS<sub>2</sub>
- Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
- Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction
- The Versatile Electronic, Magnetic and Photo‐Electro Catalytic Activity of a New 2D MA<sub>2</sub>Z<sub>4</sub> Family**
- Recent Advances on Water‐Splitting Electrocatalysis Mediated by Noble‐Metal‐Based Nanostructured Materials
- Advanced Functional Materials
- Volcano plots in hydrogen electrocatalysis - uses and abuses. [europepmc]
- Iced photochemical reduction to synthesize atomically dispersed metals by suppressing nanocrystal growth. [europepmc]
- Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering. [europepmc]
- Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions. [europepmc]
- Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential. [europepmc]
- Promoting electrocatalytic CO 2 reduction to formate via sulfur-boosting water activation on indium surfaces. [europepmc]
- Atomic and electronic modulation of self-supported nickel-vanadium layered double hydroxide to accelerate water splitting kinetics. [europepmc]
- Anomalous hydrogen evolution behavior in high-pH environment induced by locally generated hydronium ions. [europepmc]
- Three-dimensional open nano-netcage electrocatalysts for efficient pH-universal overall water splitting. [europepmc]
- Missing-linker metal-organic frameworks for oxygen evolution reaction. [europepmc]
- Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide. [europepmc]
- The hydrogen evolution reaction: from material to interfacial descriptors. [europepmc]
- Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction. [europepmc]
- Using nature's blueprint to expand catalysis with Earth-abundant metals. [europepmc]
- Engineering active sites on hierarchical transition bimetal oxides/sulfides heterostructure array enabling robust overall water splitting. [europepmc]
- Single-phase perovskite oxide with super-exchange induced atomic-scale synergistic active centers enables ultrafast hydrogen evolution. [europepmc]
- Is There Anything Better than Pt for HER? [europepmc]
- Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting. [europepmc]
- Insights into the activity of single-atom Fe-N-C catalysts for oxygen reduction reaction. [europepmc]
- Anion-Exchange Membrane Water Electrolyzers. [europepmc]
- Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments. [europepmc]
- In-plane strain engineering in ultrathin noble metal nanosheets boosts the intrinsic electrocatalytic hydrogen evolution activity. [europepmc]
- In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO 2 reduction to methanol. [europepmc]
- Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions. [europepmc]
- Precious Metal Free Hydrogen Evolution Catalyst Design and Application. [europepmc]
Related