2008/10/02 by C.R. Mariappan, C. R. Mariappan, Mariappan, C. R. +3
Materials Science · Physics and Astronomy · #Conducting polymers and applications #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #Other Condensed Matter (cond-mat.other) #cond-mat.mtrl-sci #cond-mat.other
paper · pdf · doi:10.48550/arxiv.0810.0429
arxiv created 2008/10/02 · openalex publication_date 2008/10/02 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Electro-thermal poling experiments were carried out on a bioactive glass, and the kinetics of the Na+ ion depletion layer formation under the anode was studied in-situ by means of ac impedance spectroscopy. One important finding is a linear relation between the depletion layer thickness and the applied voltage, which is in contrast to the predictions of standard space charge theory. The average electric field in the layer is independent of the voltage and is close to the dielectric breakdown field of alkali ion conducting glasses. Furthermore, we observe that the thickness of the depletion layer is established on a much shorter time scale than the resistance. We explain these results by assuming that the huge electric fields created under the anode during Na+ ion depletion lead to a strong increase of the electronic mobility in the layer and to charge compensation via extraction of electrons. It is shown that in the initial stages of the depletion process, a relative Na+ ion depletion of only 400 ppm is sufficient to generate electric fields of the order of the dielectric breakdown field.