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The Glass Transition of Quantum Hard Spheres in High Dimensions

2023/11/08 by Michael Winer, Christopher L. Baldwin, Winer, Michael +7
Engineering · Materials Science · Physics and Astronomy · #Advanced Thermodynamics and Statistical Mechanics #Disordered Systems and Neural Networks (cond-mat.dis-nn) #FOS: Physical sciences #Material Dynamics and Properties #Phase Equilibria and Thermodynamics #Quantum Physics (quant-ph) #Statistical Mechanics (cond-mat.stat-mech)

paper · pdf · doi:10.48550/arxiv.2311.04968

openalex publication_date 2023/11/08 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01

Abstract

We study the equilibrium thermodynamics of quantum hard spheres in the infinite-dimensional limit, determining the boundary between liquid and glass phases in the temperature-density plane by means of the Franz-Parisi potential. We find that as the temperature decreases from high values, the effective radius of the spheres is enhanced by a multiple of the thermal de Broglie wavelength, thus increasing the effective filling fraction and decreasing the critical density for the glass phase. Numerical calculations show that the critical density continues to decrease monotonically as the temperature decreases further, suggesting that the system will form a glass at sufficiently low temperatures for any density.

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