2020/10/05 by McEldrew, Michael, Goodwin, Zachary A. H., Zhao, Hongbo +2 · 1 citation
#Chemical Physics (physics.chem-ph) #FOS: Physical sciences #Statistical Mechanics (cond-mat.stat-mech)
paper · doi:10.48550/arxiv.2010.02091
Here we present a theory of ion aggregation and gelation of room temperature ionic liquids (RTILs). Based on it, we investigate the effect of ion aggregation on correlated ion transport - ionic conductivity and transference numbers - obtaining closed-form expressions for these quantities.The theory depends on the maximum number of associations a cation and anion can form, and the strength of their association. To validate the presented theory, we perform molecular dynamics simulations on several RTILs, and a range of temperatures for one RTIL. The simulations indicate the formation of large clusters, even percolating through the system under certain circumstances, thus forming a gel, with the theory accurately describing the obtained cluster distributions in all cases. We discuss the possibility of observing a gel phase in neat RTILs, which has hitherto not been discussed in any detail.