Identification of CIS-4, 5-Epoxy-2-Pentenal from pyrolysis of H[3]PO[4] treated cellulose

2019/12/17 by Lam, L. K., Fung, D. P., Tsuchiya, Y. +1
#cellulose #fire retardants #flammability #inflammabilité #potassium #produit de protection contre le feu #pyrolyse #pyrolysis

paper · doi:10.4224/40001748

Abstract

An important product, C[5]H[6]O[2], from the pyrolytic decomposition of phosphoric acid, treated cellulose was isolated and identified as cis-4,5-expoxy-2-pentenal. NMR, IR UV, and mass-spectral data of this product were analyzed and discussed. A method for the preparation of cis-4,5- epoxy-2-pentenal is presented, and a mechanism for its formation is proposed.

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