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FeSe(en)0.3 - Separated FeSe layers with stripe-type crystal structure by intercalation of neutral spacer molecules

2017/06/01 by Stahl, Juliane, Johrendt, Dirk
#FOS: Physical sciences #Superconductivity (cond-mat.supr-con)

paper · doi:10.48550/arxiv.1706.00314

Abstract

Solvothermal intercalation of ethylenediamine molecules into FeSe separates the layers by 1078 pm and creates a different stacking. FeSe(en)0.3 is not superconducting although each layer exhibits the stripe-type crystal structure and the Fermi surface topology of superconducting FeSe. FeSe(en)0.3 requires electron-doping for high-Tc similar to monolayers of FeSe@SrTiO3, whose much higher Tc may arise from the proximity of the oxide surface.

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