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NMR spin-lattice relaxation in molecular rotor systems

2015/07/06 by Wzietek, P.
#Chemical Physics (physics.chem-ph) #FOS: Physical sciences

paper · doi:10.48550/arxiv.1507.01419

Abstract

A general expression is derived for the dipolar NMR spin-lattice relaxation rate 1/T1 of a system exhibiting Brownian dynamics in a discrete and finite configuration space. It is shown that this approach can be particularly useful to model the proton relaxation rate in molecular rotors.

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