2024/01/05 by Babak Minaie, Minaie, Babak, S. A. Ketabi +3 · 1 citation
Engineering · Materials Science · Physics and Astronomy · #00-XX #Computational Physics (physics.comp-ph) #FOS: Physical sciences #Graphene research and applications #I.6.0 #J.2.0 #Materials Science (cond-mat.mtrl-sci) #Molecular Junctions and Nanostructures #Quantum and electron transport phenomena
paper · pdf · doi:10.48550/arxiv.2401.05429
openalex publication_date 2024/01/05 · openalex created_date 2024/01/13 · openalex updated_date 2026/07/28
In the present work, first-principles calculations based on the density functional theory (DFT), GW approximation and Bethe-Salpeter equation (BSE) are performed to study the electronic and optical properties of penta-graphene (PG) monolayer. The results indicated that PG is a semiconductor with an indirect band gap of approximately 2.32 eV at the DFT- GGA level. We found that the utilization of the GW approximation based on many-body perturbation theory led to an increase in the band gap, resulting in a quasi-direct gap of 5.35 eV. Additionally, we employed the G0W0 - RP A and G0W0 - BSE approximations to calculate the optical spectra in the absence and in the presence of electron-hole interaction, respectively. The results demonstrated that the inclusion of electron-hole interaction caused a red-shift of the absorption spectrum towards lower energies compared to the spectrum obtained from the G0W0 - RP A approximation. With the electron-hole interaction, it is found that the optical absorption spectra are dominated by the first bound exciton with a significant binding energy 3.07 eV. The study concluded that the PG monolayer, with a wider band gap and enhanced excitonic effects, holds promise as a suitable candidate for the design and fabrication of optoelectronic components.