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Modified Mott-Schottky Analysis of Nanocrystal Solar Cells

2011/12/07 by Shawn M. Willis, Cheng Cheng, Willis, Shawn M. +5
Materials Science · Engineering · Physics and Astronomy · #Quantum Dots Synthesis And Properties #Chalcogenide Semiconductor Thin Films #Semiconductor materials and interfaces

paper · pdf · doi:10.48550/arxiv.1112.1623

Abstract

Mott-Schottky analysis is adapted to determine the built-in bias (Vbi) and doping density (N) of lead sulfide-zinc oxide colloidal quantum dot heterojunction solar cells. We show that charge injection barriers at the solar cell's electrodes create a constant capacitance that distorts the junction's depletion capacitance and result in erroneous Vbi and N values when determined through Mott-Schottky analysis. The injection barrier capacitance is taken into account by incorporating a constant capacitance in parallel with the depletion capacitance.

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