2018/01/31 by Ayano Nakagawa, Nakagawa, Ayano, Makiko Nishino +26
Chemistry · Materials Science · Physics and Astronomy · #Diamond and Carbon-based Materials Research #FOS: Physical sciences #Fullerene Chemistry and Applications #Graphene research and applications #Materials Science (cond-mat.mtrl-sci) #cond-mat.mtrl-sci
paper · pdf · doi:10.48550/arxiv.1801.10258
15 pages, 4 figures
arxiv created 2018/01/31 · openalex publication_date 2018/01/31 · arxiv updated 2018/02/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Endohedral metallofullerenes have been extensively studied, since the first experimental observation of La@C60 in a laser-vaporized supersonic beam in 1985. However, all of these studies have been carried out on metallofullerenes larger than C60 such as (metal)@C82, and there are no reported purified C60-based metallofullerenes except for [Li@C60]+(SbCl6)- salt. Pure (metal)@C60 has not been obtained because of their extremely high chemical reactivity. We report here the first isolation, structural determination and electromagnetic properties of crystalline C60-based metallofullerenes, Gd@C60(CF3)5 and La@C60(CF3)5. Synchrotron X-ray single-crystal diffraction reveals that La and Gd atoms are indeed encapsulated in the Ih-C60 fullerene. The HOMO-LUMO gaps of Gd@C60 and La@C60 are significantly widened by an order of magnitude with addition of CF3- groups. Magnetic measurements show the presense of a weak antiferromagnetic coupling in Gd@C60(CF3)3 crystals at low temperatures. Gd@C60 and La@C60 might exhibit superconductivity as the electronic structures resemble those of superconducting alkali-doped C60 fullerides.